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101.
BIOLOGICAL ACTIVITIES OF PHTHALOCYANINES-X. SYNTHESES AND ANALYSES OF SULFONATED PHTHALOCYANINES 总被引:5,自引:0,他引:5
Hasrat Ali Réjean Langlois J. Richard Wagner Nicole Brasseur Benoit Paquette Johan E. VAN Lier 《Photochemistry and photobiology》1988,47(5):713-717
Abstract— Synthetic methods to obtain selectively sulfonated metallo phthalocyanines are compared. Both condensation and direct sulfonation procedures lead to mixtures of mono- to tetrasulfonated products which are resolved by reverse phase liquid chromatography in buffered aqueous-methanol. The proportion of sulfonated derivatives is examined as a function of the starting reagents in the case of the condensation method, and as a function of the temperature and reaction time in the case of the direct sulfonation procedure. The number of sulfonate groups per phthalocyanine molecule is determined by oxidative degradation of the phthalocyanine ring followed by quantitative chromatographic analysis of the sulfophthalamide and phthalamide fragments. 相似文献
102.
Boulinguiez B Le Cloirec P Wolbert D 《Langmuir : the ACS journal of surfaces and colloids》2008,24(13):6420-6424
The selection of a proper sorbent for a given application is a complex problem. The design and efficiency of adsorption processes require an equilibrium adsorption model. Linear transformation is one of the methods available to estimate the adjustable parameters of isotherm models but possesses limitations compared to nonlinear regressions. A different approach to calculate predicted equilibrium isotherm values leading to an alternative nonlinear regression is presented in this paper and compared with usual regression methods. Adsorption isotherm data of gaseous THT onto three activated carbon materials constitute an experimental basis for the discussion. Assessment of the goodness-of-fit of the Langmuir model is supported by different selected test functions. The new nonlinear approach did not obtain the best results for each test function, but raises questions about the inherent combined error in regression procedures. 相似文献
103.
Echard JP Benoit C Peris-Vicente J Malecki V Gimeno-Adelantado JV Vaiedelich S 《Analytica chimica acta》2007,584(1):172-180
The organic constituents of historical vanishes from two ancient Italian lutes and a Stradivari violin, kept in the Musée de la musique in Paris, have been characterized using gas chromatography-mass spectrometry. Results have been compared with the chromatograms and mass spectra of recent as well as old naturally aged reference materials. The three historical varnishes analyzed have been shown to be oil varnishes, probably mixtures of linseed oil with resins. Identification of diterpenoids and triterpenoids compounds, and of the resins that may have been ingredients of the varnishes, are discussed in this paper. 相似文献
104.
Barlow S Zhang Q Kaafarani BR Risko C Amy F Chan CK Domercq B Starikova ZA Antipin MY Timofeeva TV Kippelen B Brédas JL Kahn A Marder SR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(12):3537-3547
Several hexaazatrinaphthylene derivatives and a tris(thieno)hexaazatriphenylene derivative have been synthesised by reaction of the appropriate diamines with hexaketocyclohexane. The crystal structure of 2,3,8,9,14,15-hexachloro-5,6,11,12,17,18-hexaazatrinaphthylene has been determined by X-ray diffraction; this reveals a molecular structure in good agreement with that predicted by density functional theory (DFT) calculations and pi-stacking with an average spacing between adjacent molecular planes of 3.18 A. Solid-state ionisation potentials have been measured by using UV photoelectron spectroscopy and fall in the range of 5.99 to 7.76 eV, whereas solid-state electron affinities, measured using inverse photoelectron spectroscopy, vary in the range -2.65 to -4.59 eV. The most easily reduced example is a tris(thieno)hexaazatriphenylene substituted with bis(trifluoromethyl)phenyl groups; DFT calculations suggest that the highly exothermic electron affinity is due both to the replacement of the outermost phenylene rings of hexaazatrinaphthylene with thieno groups and to the presence of electron-withdrawing bis(trifluoromethyl)phenyl groups. The rather exothermic electron affinities, the potential for adopting pi-stacked structures and the low intramolecular reorganisation energies obtained by DFT calculations suggest that some of these molecules may be useful electron-transport materials. 相似文献
105.
Isothermal adsorption of Ar on single walled carbon nanotubes (SWNTs) has been studied at 77 and 87 K. The SWNTs have been grown by laser vaporization of a graphite pellet containing 0.6% (atomic) Ni/Co catalyst. The nanotubes have been prepared for argon adsorption measurements by prolonged outgassing of as-grown material in a vacuum at room temperature (295 K), at elevated temperatures of up to 475 K, and by oxidization for 2 h in dry air at 470 K. Formation of two condensed phases of Ar in the interior of SWNTs has been observed at 77 K. The low-density phase is formed at 155(5) microTorr, while the high-density phase, at 120(5) microTorr. At 87 K, only a single phase has been observed at 185(5) microTorr. Condensation at both 77 and 87 K appears to be the first-order phase transition. Onset of the quasi-one-dimensional linear (one-channel) phase and the quasi-two-dimensional monolayer (six-channel) phase formation on the external surface of bundles has been observed at 77 K near 0.0017 and 0.8 Torr, respectively, and at 87 K near 0.018 and 5 Torr, respectively. Isosteric heats of adsorption for the one-channel phase, the first external layer, and the second external layer have been determined to be equal to 137, 107, and 70 meV, respectively. 相似文献
106.
Monot Frédéric Benoit Yves Ballerini Daniel Vandecasteele Jean-Paul 《Applied biochemistry and biotechnology》1990,(1):375-386
Utilization of lipases for synthesis of esters of hydrophilic polyols has been investigated. The choice of a suitable solvent
is crucial in this type of reaction. An interesting case is fatty acid esters from neopentylpolyols, such as trimethylolpropane,
which are of great interest as high temperature lubricants. Enzymatic synthesis of trimethylolpropane tricaprylate was studied
as an alternative to chemical manufacturing. Triester production occurred only if the water produced by esterification was
continuously removed from the medium. In these condition, kinetics of appearance and transformation of mono-, di- and triesters
were determined in order to define optimal conditions. 相似文献
107.
The dilute solution properties of head-to-head polystyrene are reported. Determination of the “θ” temperature in cyclohexane has been made and compared with the “θ” temperature of the head-to-tail polystyrene (polyprotostyrene and poly-deuteriostyrene). The viscometric behaviour in a good solvent has been also examined and compared with the properties of head-to-tail polystyrenes (atactic, isotactic and deuterated). 相似文献
108.
Hou Y Jaffrezic-Renault N Martelet C Tlili C Zhang A Pernollet JC Briand L Gomila G Errachid A Samitier J Salvagnac L Torbiéro B Temple-Boyer P 《Langmuir : the ACS journal of surfaces and colloids》2005,21(9):4058-4065
To make ultrathin films for the fabrication of artificial olfactory systems, odorant biosensors, we have investigated mixed Langmuir and Langmuir-Blodgett films of odorant-binding protein/amphiphile. Under optimized experimental conditions (phosphate buffer solution, pH 7.5, OBP-1F concentration of 4 mg L(-1), target pressure 35 mN m(-1)), the mixed monolayer at the air/water interface is very stable and has been efficiently transferred onto gold supports, which were previously functionalized by self-assembled monolayers (SAMs) with 1-octadecanethiol (ODT). Atomic force microscopy and electrochemical impedance spectroscopy were used to characterize mixed Langmuir-Blodgett (LB) films before and after contact with a specific odorant molecule, isoamyl acetate. AFM phase images show a higher contrast after contact with the odorant molecule due to the new structure of the OBP-1F/ODA LB film. Non-Faradaic electrochemical spectroscopy (EIS) is used to quantify the effect of the odorant based on the electrical properties of the OBP-1F/ODA LB film, as its resistance strongly decreases from 1.18 MOmega (before contact) to 25 kOmega (after contact). 相似文献
109.
Pognon G Boudon C Schenk KJ Bonin M Bach B Weiss J 《Journal of the American Chemical Society》2006,128(11):3488-3489
A new type of very compact Pacman bis-porphyrin scaffold has been obtained in which a calix[4]arene spacer provides both cofacial preorganization and flexibility. Changes in the distance between the two tetrapyrrolic macrocycles can be triggered by electrochemistry, where closed and open conformers can be interconverted in a handclapping motion. 相似文献
110.
The first member of a new class of ditopic calix[6]arene has been synthesized, which is decorated with three N-methylimidazoles at the small rim and three 1,4-disubstituted-1,2,3-triazoles at the large rim. The coordination of a first Zn(II) cation selectively takes place at the small rim. Addition of a second equivalent results in the complexation of the three triazoles, providing a rare example of 1,2,3-triazole ligands embedded within a supramolecular system. 相似文献